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Chemical Synthesis of Insulin Analogs through a Novel Precursor                Alexander N. Zaykov, John P. Mayer, Vasily M. Gelfanov, and Richard D. DiMarchi, ACS Chem. Biol., 2014, 9 (3), pp 683–691. Insulin remains a challenging synthetic target due in large part to its two-chain, disulfide-constrained structure. Biomimetic single chain precursors inspired by proinsulin that utilize short…

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